Understanding the Curie's law calculator — concept and principle
Curie's law describes how a paramagnetic material magnetises in a field: the weaker the temperature's scrambling effect, the stronger the magnetisation. This calculator finds the Curie constant, susceptibility and magnetisation from the density of magnetic ions, their g-factor and angular momentum, and checks the result against the exact Brillouin function.
How it is calculated
- Curie constant C = μ₀ n gJ² J(J + 1) μB² ÷ (3kB), with n the number of magnetic ions per m³.
- Susceptibility χ = C ÷ T (SI, volume); magnetisation M = χB ÷ μ₀ in weak fields.
- Effective moment = gJ √(J(J + 1)) μB.
- Saturation Ms = n gJ J μB; exact M = Ms BJ(x) with x = gJ J μB B ÷ (kB T) and the Brillouin function BJ.
- The Curie law is valid when x ≪ 1.
The principle
Each magnetic ion is a tiny magnet with quantised orientations. A field favours alignment; thermal energy kBT randomises it. When the magnetic energy is much smaller than kBT, the net alignment is proportional to B ÷ T, which is Curie's law. At low temperature or strong fields, alignment approaches its maximum, the moments saturate and the Brillouin function is needed. Interactions between moments, which cause ferromagnetism or Curie–Weiss behaviour, are ignored here.
Worked example
Default inputs: n = 0.5 × 10²⁸ per m³, gJ = 2, J = 3.5 (as in Gd³⁺), T = 300 K, B = 1 T.
- Curie constant C ≈ 0.822 K; susceptibility χ = 0.822 ÷ 300 ≈ 0.00274.
- M = 0.00274 × 1 ÷ μ₀ ≈ 2,180 A/m.
- Effective moment = 2 × √(3.5 × 4.5) ≈ 7.937 μB.
- Ms = 5 × 10²⁷ × 2 × 3.5 × 9.274 × 10⁻²⁴ ≈ 324,600 A/m; M is only 0.6717% of saturation.
- x ≈ 0.01567, so the Brillouin result is also 2,180 A/m: the Curie law is valid.
| Landé g-factor g_J | Magnetization M, Curie law (A/m) |
|---|---|
| 0.5 | 136.3 |
| 1 | 545.1 |
| 1.5 | 1,226 |
| 2 | 2,180 |
| 2.5 | 3,407 |
| 3 | 4,906 |
| 4 | 8,721 |
How to read the result
At room temperature even a 1 T field aligns well under 1% of the moments, which is why paramagnets are only weakly magnetic. Cooling to a few kelvin or applying many tesla pushes x towards 1 and the magnetisation towards saturation, which is exploited in magnetic refrigeration and low-temperature physics.
Common mistakes
- Confusing SI and CGS susceptibilities (they differ by 4π).
- Using the ion density per cm³ instead of per m³.
- Applying Curie's law at low temperature or high field without checking x.
- Using g = 2 for ions with strong orbital contributions.
Frequently asked questions
What is Curie's law?
χ = C ÷ T: the susceptibility of an ideal paramagnet is inversely proportional to temperature.
When does Curie's law fail?
At low temperature or strong field, when moments saturate, and in materials with strong interactions.
What is the Brillouin function?
The exact quantum expression for the average alignment of moments with angular momentum J in a field.
Sources: Kittel, C., Introduction to Solid State Physics, 8th ed. Wiley (Curie law, Brillouin function) · Blundell, S., Magnetism in Condensed Matter. Oxford University Press